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What is Metal-Nonmetal Transition

Handbook of Research on Advancements in Supercritical Fluids Applications for Sustainable Energy Systems
A phenomenon that occurs owing to decreasing number of carriers (conduction electrons and holes), decreasing carrier mobility or group velocity in a material. In a fluid system, typical evidence of the transition is that high metallic electrical conductivity is reduced into a poor insulating one.
Published in Chapter:
X-Ray Scattering Studies of Expanded Fluid Metals
Kazuhiro Matsuda (Kumamoto University, Japan) and Masanori Inui (Hiroshima University, Japan)
DOI: 10.4018/978-1-7998-5796-9.ch006
Abstract
Fluid metals exhibit significant properties of thermodynamic-state dependence, since the inter-particle interaction among the constituents (electrons and ions) considerably changes depending on their thermodynamic conditions. The authors have thus far carried out X-ray scattering experiments of fluid metals in the expanded state, which have enabled them to gain insight into microscopic understanding of the structural and electronic properties of fluid metals. The purpose of this chapter is to provide intriguing aspects of fluid metals originated from the existence of conduction electrons, which distinguishes fluid metals from non-conducting fluids, through the results of fluid rubidium and mercury.
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