Triazepines Compounds as Novel Synthesized Corrosion Inhibitors: State of Play and Perspectives

Triazepines Compounds as Novel Synthesized Corrosion Inhibitors: State of Play and Perspectives

Khaoula Alaoui, Ashraf Abousalem, Burak Tüzün, Younes El Kacimi
DOI: 10.4018/978-1-7998-2775-7.ch007
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Abstract

This chapter describes some recent good works in the field of metallic corrosion monitoring using Triazepine carboxylate inhibitors in hydrochloric acidic media. The different sections of this chapter cover electrochemical measurements and theoretical investigations. This review reveals Triazepine carboxylate compounds as very good inhibitors for mild steel in hydrochloric medium. The inhibition action of all Triazepine carboxylates compound studied was performed via adsorption on mild steel surface. Comparison between several adsorption isotherms reveal that the adsorption was spontaneous and followed Langmuir isotherm in HCl for all inhibitors and all studied temperatures. Kinetic and thermodynamic parameters for all inhibitors led to suggest the occurrence of chemical mechanism and also the spontaneity of the adsorption process on mild steel surface. The corrosion inhibition mechanism was also compared and discussed with the light of some Triazepine carboxyale compounds constituents.
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Background

Mild steel is applied to approximately the entire industrial field for the reason of its excellent properties. However, its corrosion usually results in enormous financial losses and potential security problems where the protection technology has attracted the interest of several researchers (Jiang, 1995; Popova, 2007; Alaoui, 2018). Among these technologies, chemical inhibitors take a significant role for iron corrosion protection for the reason of their economy and convenience (El Kacimi, 2018; Tang, 2005; Oguzie, 2004). Today, new compounds have many bonds or heteroatoms in their structures were used. Many organic compounds were employed for iron corrosion in acidic media (Serrar, 2017; Sasikumar, 2015).

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